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stabilizing substituents

См. также в других словарях:

  • Electrophile — In chemistry, an electrophile (literally electron lover ) is a reagent attracted to electrons that participates in a chemical reaction by accepting an electron pair in order to bond to a nucleophile. Because electrophiles accept electrons, they… …   Wikipedia

  • Hyperconjugation — In organic chemistry, hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non bonding p orbital or antibonding π orbital or filled π orbital, to give an extended… …   Wikipedia

  • Polychlorinated biphenyl — PCBs redirects here. For printed circuit boards, see printed circuit board. Labelling transformers containing PCBs …   Wikipedia

  • 1,3-Dipolar cycloaddition — The 1,3 dipolar cycloaddition, also known as the Huisgen cycloaddition or Huisgen reaction, [1][2] is an organic chemical reaction belonging to the larger class of concerted, pericyclic cycloadditions. It is the reaction between a 1,3 dipole and… …   Wikipedia

  • Tiffeneau-Demjanov rearrangement — The Tiffeneau Demjanov rearrangement (TDR) the chemical reaction of 1 aminomethyl cycloalkanols with nitrous acid to form an enlarged cycloketone.Ref|Tiffeneau1937After being in existence for over 65 years, the reaction is popular among organic… …   Wikipedia

  • Cation-pi interaction — is a noncovalent molecular interaction between the face of an electron rich pi system (e.g. benzene, ethylene) with an adjacent cation (e.g. Li+, Na+). This unusual interaction is an example of noncovalent bonding between a monopole (cation) and… …   Wikipedia

  • Discovery and development of angiotensin receptor blockers — The angiotensin receptor blockers (ARBs), also called angiotensin (AT1) receptor antagonists or sartans, are a group of anti hypertensive drugs that act by blocking the effects of the hormone angiotensin II (Ang II) in the body, thereby lowering… …   Wikipedia

  • Acid dissociation constant — Acetic acid, a weak acid, donates a proton (hydrogen ion, high …   Wikipedia

  • Persistent carbene — A stable carbene: isolated 1,3 dimesitylimidazol 2 ylidene in a Schlenk flask (stir bar also present). A persistent carbene (also known as stable carbene or Arduengo carbene) is a type of carbene demonstrating particular stability. The best known …   Wikipedia

  • Dakin oxidation — The Dakin oxidation The Dakin oxidation is an organic redox reaction in which an ortho or para hydroxylated phenyl aldehyde (2 hydroxybenzaldehyde or 4 hydroxybenzaldehyde) or ketone reacts with hydrogen pero …   Wikipedia

  • Tiffeneau–Demjanov rearrangement — The Tiffeneau Demjanov rearrangement (TDR) is the chemical reaction of a 1 aminomethyl cycloalkanol with nitrous acid to form an enlarged cycloketone. The Tiffeneau–Demjanov ring expansion, Tiffeneau–Demjanov rearrangement, or TDR, provides an… …   Wikipedia

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